ABSTRACT
AIM To study the chemical constituents from the twigs and leaves of Cryptomeria fortunei Hooibrenk ex Otto et Dietr.METHODS The ethyl acetate fraction of 95％ ethanol extract from C.fortunei was isolated and purified by silica,MCI,and Sephadex LH-20 column,then the structures of obtained compounds were identified by physicochemical properties and spectral data.RESULTS Eleven compounds were isolated and identified as isopimaric acid (1),sandaracopimaric acid (2),acetylisocupressic acid (3),imbricataloic acid (4),isocupressic acid (5),pinifolic acid (6),13-epicupressic acid (7),19-acetylagathadiol (8),agatadiol (9),phytol (10),elemol (11).CONCLUSION Compounds 1-10 are identified as diterpenoids and compound 11 is identified as sesquiterpenoid;Compounds 2,3,6-11 are obtained from this plant for the first time.
ABSTRACT
Objective To study the chemical constituents from the aerial parts of Artemisia lavandulaefolia. Methods The constituents were isolated and purified by various column chromatographic techniques, and their structures were identified by spectroscopic analysis. Results Eleven compounds were isolated from 95% ethanol aqueous extract of A. lavandulaefolia and the structures were identified as (4R,5R,7R,10R)-4-hydroxy-eudesma-2,11-dien-1-one (1), 5-epi-eudesma-4(15)-ene-1β,6β-diol (2), eudesma-4(15)-ene-1β,6α-diol (3), methyl 3-oxo-eudesma-1,4,11(13)-trien-12-oate (4), 11β,13-dihydrosantamarin (5), anthemidin (6), scopoletin (7), paeonol (8), ethyl caffeate (9), espeletone (10), and (1R*,2S*,3S*,4S*)-mentha-1,2,3,4-tetrol (11). Conclusion Compound 1 is a new compound named artemilavanone A, and compounds 2-11 are isolated from this plant for the first time.
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Objective: To study the chemical constituents from the twigs and leaves of Fokienia hodginsii. Methods: The compounds were separated and purified by chromatography and their structures were determined by spectroscopic data. Results: Fourteen compounds were isolated from 95% ethanol extract of F. hodginsii and identified as savinin (1), gadain (2), dihydrosesamin (3), hinokinin (4), 7-oxohinokinin (5), puviatilol (6), umbelliferone (7), phytol (8), catechin (9), amentoflavone (10), quercetin-3-O-α-L-rhamnoside (11), salicyl alcohol (12), vanillin (13), and coniferaldehyde (14). Conclusion: Compounds 1-14 are isolated from this plant for the first time.
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Objective: To study the chemical constituents from fruits of Michelia yunnanensis. Methods: The chemical constituents were isolated and purified by column chromatographies on silica gel and Sephadex LH-20. Their structures were elucidated on the basis of spectroscopic data. Results: Twelve compounds were isolated from methanol extract of the fruits of M. yunnanensis and the structures were identified as 13-methoxy-11β, 13-dihydrocostunolide (1), lanuginolide (2), tulipinolide (3), lipiferolide (4), costunolide (5), parthenolide (6), 11β, 13-dihydroparthenolide (7), 4α, 5β-epoxy-13-methoxy-11βH-germacra-1 (10)-en-12, 6α-olide (8), cyperusol C (9), aromadendra-4β, 10α-diol (10), 9-oxonerolidol (11), and 11, 13-dehydrocompressanolide (12). Conclusion: Compound 1 is isolated as a new natural product. 1H-NMR and 13C-NMR data of compounds 1 and 2 are reported for the first time. Except compound 6, other compounds are isolated from this plant for the first time.
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Objective To study the chemical constituents from the leaves of Magnolia grandiflora. Methods The chemical constituents were isolated and purified by various column chromatographic techniques, including silica gel and Sephadex LH-20, and the structures were identified by spectroscopic analyses. Results Eight sesquiterpenoids were isolated from 70% aq. acetone extract of M. grandiflora and the structures were identified as 12,13-diacetoxy-eudesma-4α,6α,11-triol (1), 12,13-diacetoxy-5αH-guaia-1 (10)-en-4α,6α,11-triol (2), 11,13-dehydrocompressanolide (3), compressanolide (4), α-santonin (5), 1β-hydroxyl-11βH-eudesma-3- en-12,6α-olide (6), β-dictyopterol (7), and 12α-methoxy-germacran-1(10), 4,11(13)-trien-12,6α-acetal (8). Conclusion Compounds 1 and 2 are new compounds named as magnogranol A and B, and compounds 4-8 are isolated from this plant for the first time.
ABSTRACT
Five cassane diterpenes were isolated from the 95% ethanol extract of the seeds of Caesalpinia bonduc (Leguminosea) by a combination of various chromatographic methods, including silica gel, Sephadex LH-20, and semi-preparative HPLC. On the basis of spectroscopic techniques, their structures were identified as 3β-acetoxy-cassa-12,14(17),15-trien-7β-ol (1), caesalmin C (2), caesall E (3), caesalpinin MJ (4), and 1-deacetylcaesalmin C (5). Among them, compound 1 is a new compound and 2, 4, 5 were isolated from the plant for the first time.